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排序方式: 共有315条查询结果,搜索用时 78 毫秒
71.
Nobuo Yamada Dr. Hiroki Noguchi Yoshifumi Orimoto Dr. Yutaka Kuwahara Prof. Dr. Makoto Takafuji Shaheen Pathan Dr. Reiko Oda Almara Mahammadali Rahimli Prof. Dr. Mahammadali Ahmed Ramazanov Prof. Dr. Hirotaka Ihara 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(43):10141-10148
In this work, a new class of totally organic fluorescent nanogel particles and their exceptionally specific behaviors based on their unique structures are introduced, which draws a sharp line from conventional fluorophore-doped and fluorophore-branched-type particles. The nanogel particles, the diameter of which could be controlled by adjusting reaction conditions, such as the solvent system, were spontaneously fabricated with a spherical shape by direct polymerization of non-heterocyclic aromatic compounds, such as 2,6-dihydroxyanthracene, 2,6-dihydroxynaphthalene, and 9,9-bis(4-hydroxyphenyl)fluorene with triazinane as the cross-linker. A fluorophoric moiety formed from a polymer main chain was realized in the particle, and consequently, the resultant content of the fluorophoric moiety was around 70–80 wt % per particle. The uniqueness and versatility of the particles can be emphasized by their good compatibility with various solvents due to their amphiphilic and ampholytic swelling properties, but also by their remarkable fluorescent solvatochromism in the dispersion state. Furthermore, these behaviors were preserved even in their polymer composite system. This study also demonstrates that various fluorescent polymer films can be fabricated with emission color control due to memorization of the solvatochromism phenomenon of the dispersed fluorescent nanoparticles. 相似文献
72.
73.
Mizue Fujio Toshikazu Adachi Yoshifumi Shibuya Akihisa Murata Yuho Tsuno 《Tetrahedron letters》1984,25(40):4557-4560
Substituent effects of p-MeO and p-MeS groups deactivated by additional m-substituents in cumyl and α-phenylethyl solvolyses were studied to provide evidence for the higher resonance demand in the α-phenylethyl system. 相似文献
74.
Yutaka Nagai Nakahara Kouji Yoneyama Yoshifumi Kawano Katsuyasu Tanaka Katsumi Nakata Ryouhei 《Journal of Physics and Chemistry of Solids》2004,65(11):1861-1870
The characteristics of high-temperature ionic thermocurrent (HT ITC) in CaF2 doped with different sodium concentrations were studied by the Teflon-insulated electrode ITC method. It was shown that, with increasing sodium concentration, the HT ITC band moved toward a Na+-FV dipole band with a peak at 162 K. The results of analyses of the HT ITC spectra using an equivalent electric circuit proved that the activation energy of space charge migration related to HT ITC was also strongly dependent on the doped sodium concentrations if varied from 0.94 to 0.46 eV with increasing sodium concentration in our ITC study. In addition, the broadening of the Na+-FV dipole band was observed in 3 nominal mole% NaF-doped CaF2, which was accompanied by a considerable decrease of the activation energy from 0.46 to 0.29 eV without showing marked temperature shifts of the peak ITC bands. 相似文献
75.
Hiroyuki Usui Yoshifumi Watanabe Munefumi Kanao 《Journal of heterocyclic chemistry》1993,30(2):551-552
The preparation of bicyclic 1,3,5-triazine-2,4(3H)-diones 3 has been investigated. Diphenyl iminodicarboxylate ( 2 ) reacted smoothly with cyclic amidines to give bicyclic triazinediones in good yields. 相似文献
76.
Pyrimido[5,4-
]pteridine
-oxide (1) oxidizes efficiently benzene, toluene, and anisole under UV irradiation to give the corresponding phenol derivatives 4, though the easiness of the reaction significantly depends upon the nature of the substituents on the benzene ring. 相似文献
77.
Shouhei Toyoda Yoshifumi Yamaguchi Masataka Hiwatashi Yasuhiko Tomonari Hiroto Murakami Dr. Naotoshi Nakashima Prof. 《化学:亚洲杂志》2007,2(1):145-149
We designed and synthesized 4‐dodecyloxybenzenediazonium tetrafluoroborate ( 1 ), which preferentially reacts with metallic single‐walled carbon nanotubes (SWNTs) by kinetic control. We first determined the suitable experimental conditions for the preferential reaction of 1 with individually dissolved SWNTs by monitoring the decrease in absorbance for the metallic SWNT in the range of 400–650 nm in the absorption spectrum of the SWNTs. The reacted SWNTs were thoroughly rinsed with THF to obtain THF‐insoluble SWNTs. The Raman spectrum of the THF‐insoluble SWNTs showed a strong peak near 180 cm?1, which corresponds to a semiconducting breathing band. The metallic breathing bands (≈220 cm?1) and Breit–Wingner–Fano (BWF) modes (1520 cm?1) corresponding to the metallic SWNTs were much weaker than those of the pristine SWNTs. We also confirmed that metallic peaks in the range of 400–650 nm in the absorption spectrum of THF‐insoluble SWNTs that were individually dissolved in an aqueous micelle of sodium cholate were almost nondetectable. All the results indicate that the THF‐insoluble SWNTs are semiconducting. 相似文献
78.
79.
Huang F Li J Wang L Dong T Tu J Torimoto Y Sadakata M Li Q 《The journal of physical chemistry. B》2005,109(24):12032-12037
The hydrogen anion (H-) and other anionic species (O-, OH-, e-) in the gas phase, emitted from the synthesized crystal surface of 12 CaO x 7 Al2O3-H- (C12A7-H-), have been observed. The emission intensity of all the anionic species strongly depends on the sample surface temperature and the extraction field. H- has the highest emission branch ratio, and the extraction field can reduce its apparent activation energy. H- emission current at a microA/cm2-level has been achieved, which is about 4 orders of magnitude higher than that obtained from the thermal desorption process of CaH2. The observed anions of H- and OH- are attributed to their migration from the C12A7-H- cages onto the surface [i.e., Y-(cages) --> Y-(surface) --> Y-(gas phase) (Y = H, OH)]. The weak O- and electron emission would both arise from the dissociation of O2-: O2-(surface) --> O-(surface) + e-(surface) --> O-(gas phase) + e-(space). 相似文献
80.
The characteristic sampling dynamics of importance samplings driven by the Tsallis weight [C. Tsallis, J. Stat. Phys. 52, 479 (1988)] has been analyzed in terms of recently developed Langevin stochastic model by considering the effects of the density of states and the potential smoothing of the Tsallis transformation. Our study reveals that the fixed points, which are determined by the crossing points of the statistical temperature and the Tsallis effective temperature, play a critical role in overall dynamics of the Tsallis statistics sampling. The dynamical origin of enhanced conformational searches of the Tsallis weight has been investigated by unveiling the intimate relationship between the sampling dynamics and the stability change of corresponding fixed points. Based on this stochastic analysis, we propose one effective method to realize a broad energy distribution in the Tsallis statistics sampling by determining optimal Tsallis parameters systematically based on preliminary canonical samplings. The effectiveness of our method has been validated in the folding simulation of Met-Enkephalin and liquid-solid transition simulation of Lennard-Jones cluster systems. 相似文献